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Kirihara Akaya (2nd year) One of, if not the earliest rival to appear in the series. His great talent at tennis enables him to beat several seniors to earn his place as regular in the Rikkai tennis club. Is one of the roughest characters in the series, and has a 'bloodshot' and 'devil' mode. Both activate when he is extremely frustrated or angry. Will replace Yukimura Seiichi as captain of the Rikkai Daigaku Fuzoku Chuu tennis club captian next year.
Yukimura Seiichi (3rd year) Called the 'Child of God' and is one of the three demons, or trioka of Rikkaidai. Underwent surgery during the Kantou match that Rikkaidai had with Seigaku. In the national finals lost to Echizen Ryoma by 4-6.
Sanada Genichirou (3rd year) Known as the Emperor. Temporarily took over the role as captain for the Rikkai tennis club when Yukimura had to go to the hospital for surgery. Lost to Echizen Ryoma in the Kantou finals. Holds a bitter three-way rivalry with Atobe and Tezuka. Would've lost to Atobe if Yukimura had not stopped their match. Won against Tezuka in the Nationals finals.
Yanagi Renji (3rd year) The lesser of the Three Demons. Is known as Rikkaidai's Data Master. Is childhood friends with Inui Sadaharu of Seishun Gakuen. Played Singles 3 during the Kantou finals against Inui Sadaharu, and Doubles 2 with Kirihara Akaya against Inui-Kaidoh pair during the Nationals finals.
Niou Masaharu (3rd year) The petenshi, or trickster of Rikkaidai. Creates an illusion of a player he masquerades, and is able to copy the person's tennis moves flawlessly. The illusion was thought to be perfect, until Fuji Syuusuke proved that he is unable to copy one move from the tennis player he imitates. He is the only one who dares to stand up against Sanada, as proven when Sanada asks everyone to slap him for his loss, which he readily did so. Played doubles with Yagyuu Hiroshi in the Kantou finals and defeated Seigaku's Golden Pair with a crushing 6-2. They masqueraded as each other so perfectly until even their own teammates didn't know. Played Singles 2 in the Nationals finals and lost to Fuji Syuusuke.
Yagyuu Hiroshi (3rd year) Rikkaidai's Gentleman. In the anime, he was sought out by Niou Masaharu from his golf club to play tennis. His best move is the "Laser Beam". A shot that is very fast and almost impossible to return. He played doubles with Niou Masaharu in the Kantou finals, and switched identities with him. Their doubles pairing has been unbeatable so far. Even though they delivered a crushing 6-2 defeat to the Golden Pair, Rikkaidai lost all 3 singles, thus resulting in Seigaku clinching the tournament.
Marui Bunta (3rd year) Is generally perceived as cheerful, and is Hyotei Gakuen's Akutagawa Jirou's idol. Is seen to be chewing bubblegum during a match, besides eating cake before entering one. Self-proclaimed tensai of Rikkai, and Rikkaidai's very own volley specialist. In the manga, he crushed the Momo-Kaidoh pair 6-1 with Jackal, wheras the match in the anime shows that it ended at a close 7-5. Lost in the Nationals to the Golden Pair.
Jackal Kuwahara (3rd year) Half-brazilian, is known as Rikkaidai's "iron wall of defense". He plays doubles with Marui Bunta. Was shown to shave his head in the match against Momo-Kaidoh pair, signifying that he wasn't scared of them at all. Lost to the Golden Pair in the Nationals.